Q1 / 75 · JEE Main 2026 (04 April Shift 1) · Chemistry

Number of moles and number of molecules in $1.4187$ L of $SO_2$ at STP respectively are:

  • A
    $0.1266; 3.812 \times 10^{22}$
  • Correct answer
    B
    $0.0633; 3.812 \times 10^{22}$
  • C
    $0.1266; 7.6238 \times 10^{22}$
  • D
    $0.0633; 7.6238 \times 10^{22}$

Solution

Volume of $SO_2$ at STP $= 1.4187$ L

Molar volume of an ideal gas at STP is approximately $22.414$ L.

Number of moles $n = \dfrac{\text{Volume}}{\text{Molar Volume}} = \dfrac{1.4187}{22.414} = 0.0633$

Number of molecules $= n \times N_A$

Number of molecules $= 0.0633 \times 6.022 \times 10^{23} = 3.812 \times 10^{22}$

Answer: $0.0633; 3.812 \times 10^{22}$

Hence, the correct answer is option: 'B'.

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