Q39 / 160 · AP EAMCET 2023 (19 May Shift 1) · Chemistry

The preferred reagent for the following conversion is $$ \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{COOH} \rightarrow \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{COCl} $$

  • A
    $\mathrm{HCl}$
  • B
    $\mathrm{HOCl}$
  • Correct answer
    C
    $\mathrm{SOCl}_2$
  • D
    $\mathrm{NaOCl}$

Solution

A carboxylic acid can be converted into its functional derivative ; acyl halide by use of thionyl chloride $\mathrm{SOCl}_2$. Figure
This reaction is a nucleophilic acyl substitution with $\mathrm{SOCl}_2$ acting as a good nucleophilic reagent.

Hence, the correct answer is option: 'C'.

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