Q72 / 180 · JIPMER 2019 · Chemistry

The magnetic moment of $\mathrm{Ni}^{2+}$ ion (atomic number of $\mathrm{Ni}=28$ ) in BM unit is

  • A
    1.73
  • B
    4.81
  • C
    5.96
  • Correct answer
    D
    2.84

Solution

$\mathrm{Ni}_{28}=[\mathrm{Ar}]_{18} 3 \mathrm{~d}^8 4 \mathrm{~s}^2, \mathrm{Ni}^{2+}=[\mathrm{Ar}]_{18} 3 \mathrm{~d}^8 4 \mathrm{~s}^2$ Figure Number of unpaired electrons $=2$ Magnetic moment, $\mu=\sqrt{n(n+2)}=\sqrt{2(2+2)}=\sqrt{8}=2.84 \mathrm{BM}$

Hence, the correct answer is option: 'D'.

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