Q52 / 200 · NEET 2003 · Chemistry

The ions $\mathrm{O}^{2-}, \mathrm{F}^{-}, \mathrm{Na}^{+}, \mathrm{Mg}^{2+}$ and $\mathrm{Al}^{3+}$ are isoelectronic. Their ionic radii show:

  • A
    a significant increase from $\mathrm{O}^{2-}$ to $\mathrm{Al}^{3+}$
  • Correct answer
    B
    a significant decrease from $\mathrm{O}^{2-}$ to $\mathrm{Al}^{3+}$
  • C
    an increase from $\mathrm{O}^{2-}$ to $\mathrm{F}^{-}$and then decrease from $\mathrm{Na}^{+}$to $\mathrm{Al}^{3+}$
  • D
    a decrease from $\mathrm{O}^{2-}$ to $\mathrm{F}^{-}$and then increase from $\mathrm{Na}^{+}$to $\mathrm{Al}^{3+}$

Solution

Ionic radii decrease with the increase in charge on species.

Hence, the correct answer is option: 'B'.

Relevant Questions