Q1 / 90 · JEE Main 2021 (31 Aug Shift 2) · Chemistry

The incorrect expression among the following is :

  • A
    For isothermal process wreversible =-nRT lnVf Vi
  • Correct answer
    B
    lnK=ΔH°-TΔS°RT
  • C
    ΔGSystem ΔSTotal =-T (at constant P)
  • D
    K=e-ΔG°/RT

Solution

ΔG=ΔG°+RT lnQ at equilibrium Q=Keq and ΔG=0

 ΔG°=-RT lnKeq and ΔG°=ΔH°-TΔS°

 ΔH°-TΔS°=-RTlnKeq So, lnKeq=-ΔH°-TΔS°RT=-ΔH°+TΔS°RT

Hence, the correct answer is option: 'B'.

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