Q42 / 97 · NTA Abhyas (JEE Main) 2020 · Chemistry · Solutions

The freezing point of equimolal aqueous solution will be highest for

  • A
    C6H5N+H3Cl- (aniline hydrochloride)
  • B
    Ca(NO3)2
  • C
    La(NO3)3
  • Correct answer
    D
    C6H12O6 (Glucose)

Solution

ΔTf∝m×i
m = morality, i = Vant Hoff factor
Except glucose, all other a electrolytes are undergoing dissociation so (i>1) . Glucose is non electrolyte, i=1 . so it has least value of ΔTf hence its freezing point is maximum.

Hence, the correct answer is option: 'D'.

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