Q18 / 160 · TS EAMCET 2021 (06 Aug Shift 1) · Chemistry

The fluoride ions make the enamel of teeth much harder by converting, which of the following substance/compound

  • A
    $\left[3 \mathrm{Mg}_3\left(\mathrm{PO}_4\right)_2 \cdot \mathrm{Ca}(\mathrm{OH})_2\right]$
  • Correct answer
    B
    $\left[3 \mathrm{Ca}_3\left(\mathrm{PO}_4\right)_2 \cdot \mathrm{Ca}(\mathrm{OH})_2\right]$
  • C
    $\left[3 \mathrm{Ca}_3\left(\mathrm{PO}_4\right)_2 \cdot \mathrm{CaF}_2\right]$
  • D
    $\left[3 \mathrm{Ca}_3\left(\mathrm{PO}_4\right)_2 \cdot \mathrm{MgCl}_2\right]$

Solution

Teeth enamel contain $\left[3 \mathrm{Ca}_3\left(\mathrm{PO}_4\right)_2 \cdot \mathrm{Ca}(\mathrm{OH})_2\right]$ which on reacting with fluoride ion is converted into $\left[3 \mathrm{Ca}_3\left(\mathrm{PO}_4\right)_2 \cdot \mathrm{CaF}_2\right]$ much harder. Figure

Hence, the correct answer is option: 'B'.

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