Q8 / 200 · WBJEE 2014 · Chemistry

The correct order of decreasing $\mathrm{H}-\mathrm{C}-\mathrm{H}$ angle in the following molecule is Figure

  • A
    I>II>III
  • Correct answer
    B
    II>I>III
  • C
    III>II>I
  • D
    I>III>II

Solution

$\mathrm{H}-\mathrm{C}-\mathrm{H}$ bond angle is about $120^{\circ}$, when $\mathrm{C}$ is bonded through a double bond but in case of $\mathrm{CH}_{4}$ the $\mathrm{H}-\mathrm{C}-\mathrm{H}$ bond angle is only $109^{\circ} \mathrm{2B}^{\prime}$ Cyclic compounds have a $\mathrm{H}-\mathrm{C}-\mathrm{H}$ bond angle Feater than $109^{\circ} 28^{\prime}$ due to hindrance. Thus, the correct order of $1 \mathrm{H}-\mathrm{C}-\mathrm{H}$ bond angle is Figure

Hence, the correct answer is option: 'B'.

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