Q23 / 90 · KVPY 2017 (19 Nov SB/SX) · Chemistry

The consecutive reaction $\mathrm{X} \rightarrow \mathrm{Y} \rightarrow \mathrm{Z}$ takes place in a closed container. Initially, the container has $\mathrm{A}_{0}$ moles of $\mathrm{X}$ (and no $\mathrm{Y}$ and $\mathrm{Z}$ ). The plot of total moles of the constituents in the container as a function of time will be

  • A
    Figure
  • Correct answer
    B
    Figure
  • C
    Figure
  • D
    Figure

Solution

$$ \begin{array}{llll} & \mathrm{X} \longrightarrow & \mathrm{Y} \longrightarrow & \mathrm{Z} \\ \mathrm{t}=0 & \mathrm{~A}_{0} & 0 & 0 \\ \mathrm{t}=\mathrm{t} & \mathrm{A}_{0}-\mathrm{x} & \mathrm{y} & \mathrm{Z} \end{array} $$ So total moles of constituents will be more at any time ' $t^{\prime}$ as compared to $t=0$

Hence, the correct answer is option: 'B'.

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