Q58 / 180 · KCET 2019 · Chemistry

Resonance effect is not observed in

  • A
    \( \mathrm{CH}_{2}=\mathrm{CH}-\mathrm{Cl} \)
  • Correct answer
    B
    \( \mathrm{CH}_{2}=\mathrm{CH}-\mathrm{CH}_{2}-\mathrm{NH}_{2} \)
  • C
    \( \mathrm{CH}_{2}=\mathrm{CH}-\mathrm{CH}=\mathrm{CH}_{2} \)
  • D
    \( \mathrm{CH}_{2}=\mathrm{CH}-\mathrm{C}=\mathrm{N} \)

Solution

(B)
In \( \mathrm{H}_{2} \mathrm{C}=\mathrm{CH}-\mathrm{CH}_{2}-\mathrm{NH}_{2} \), the lone pair of \( \mathrm{N} \) is not on adjacent carbon with \( \pi \) bond. (Not in conjugatedsystem.)

Hence, the correct answer is option: 'B'.

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