Q10 / 180 · KCET 2013 · Chemistry
Mesomeric effect involves
- Correct answerAdelocalisation of $\pi$-electrons
- Bdelocalisation of $\sigma$-electrons
- Cpartial displacement of electrons
- Ddelocalisation of $\pi$ and $\sigma$-electrons
Solution
Resonance or mesomeric effect is defined as, the polarity produced in the molecule by the interaction of two $\pi$-bonds or between a $\pi$-bond and a lone pair of electrons present on an adjacent atom. There are two types of mesomeric effect.
$+M$ effect is observed when direction of electron displacement is away from an atom or substituent group attached to the conjugated system e.g., - halogen, $-\mathrm{OH},-\mathrm{NH}_{2}$ etc. On the other hand, - M effect is observed when the transfer of electrons is towards the atom or substituent group attached to the conjugted systems, e.g., $-\mathrm{NO}_{2},-\mathrm{COOH}$ etc.
Hence, the correct answer is option: 'A'.