Q23 / 120 · JEE Advanced 2006 · Chemistry
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$$
\mathrm{RCONH}_2 \text { is converted into } \mathrm{RNH}_2 \text { by means of Hofmann bromamide degradation. }
$$
In this reaction, $R \mathrm{CONHBr}$ is formed from which this reaction has derived its name. Electron donating group at phenyl activates the reaction. Hofmann degradation reaction is an intramolecular reaction.Question:
What are the constituent amines formed when the mixture of (i) and (ii) undergoes Hofmann bromamide degradation?

In this reaction, $R \mathrm{CONHBr}$ is formed from which this reaction has derived its name. Electron donating group at phenyl activates the reaction. Hofmann degradation reaction is an intramolecular reaction.Question: What are the constituent amines formed when the mixture of (i) and (ii) undergoes Hofmann bromamide degradation?

- A

- Correct answerB

- C

- D

Solution

$$ \text { Since the overall reaction is intermolecular, hence there will be no effect on product formation. } $$
Hence, the correct answer is option: 'B'.