Q14 / 60 · JEE Advanced 2009 (Paper 1) · Chemistry

Paragraph: A carbonyl compound $P$, which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration to give an olefin $Q$. Ozonolysis of $Q$ leads to a dicarbonyl compound $R$, which undergoes intramolecular aldol reaction to give predominantly $S$. $$ P \underset{\text { (ii) } \mathrm{H}^{+}, \mathrm{H}_2 \mathrm{O}}{\stackrel{\text { (i) } \mathrm{MeMgBr}}{\longrightarrow}} \mathrm{Q} \underset{\text { Heat }}{\stackrel{\mathrm{O}_3 / \mathrm{Zn}-\mathrm{H}_2 \mathrm{O}}{\longrightarrow}} \mathrm{P} $$ (iii) $\mathrm{H}_2 \mathrm{SO}_4$ /HeatQuestion: $$ \text { The structures of the products } Q \text { and } R \text {, respectively, are } $$

  • Correct answer
    A
    Figure
  • B
    Figure
  • C
    Figure
  • D
    Figure

Hence, the correct answer is option: 'A'.

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