Q14 / 160 · TS EAMCET 2021 (05 Aug Shift 1) · Chemistry

Match the following.
  Column-1
Reaction
  Column-2
Main product
A SO3⟶heavy water I C2D2
B CaC2⟶heavy water (excess) II CD4
C Al4C3⟶heavy water (large excess) III D2SO3
    IV C2D4
    V D2SO4

The correct match is

  • A
    A B C
    III I IV
  • B
    A B C
    III IV II
  • Correct answer
    C
    A B C
    V I II
  • D
    A B C
    V I IV

Solution

SO3⟶D2O D2SO4Same as SO3⟶H2O H2SO4

CaC2⟶D2O (excess) Ca(OD)2 + D2C2Same as CaC2⟶H2O (excess) Ca(OH)2 + H2C2

Al4C3 +12 D2O ⟶ (large excess) 4Al(OD)3 + 3CD4Same as Al4C3 +12 H2O ⟶ (large excess) 4Al(OH)3 + 3CH4

Hence, the correct answer is option: 'C'.

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