Q37 / 120 · JEE Advanced 2006 · Chemistry

Match the extraction processes listed in column I with metals listed in column II. Figure

  • A
    (A) P,S, (B) R, (C) P,Q, (D) P,S
  • B
    (A) Q,S, (B) R, (C) S, (D) S
  • C
    (A) P,R, (B) P, R, (C) Q, (D) R
  • Correct answer
    D
    (A) P,R, (B) P, (C) Q, (D) S

Solution

Column I Column II (A) Self reduction $\left[\begin{array}{c}P \text { - Lead } \\ R \text { - Copper }\end{array}\right]$ $$ \begin{aligned} & \text { i.e., } A \rightleftarrows P \text { and } R \\ & \text { In lead metal } \\ & \qquad\left\{\begin{array}{c} 2 \mathrm{PbS}+3 \mathrm{O}_2 \longrightarrow 2 \mathrm{PbO}+2 \mathrm{SO}_2 \\ 2 \mathrm{PbO}+\mathrm{PbS} \longrightarrow 3 \mathrm{~Pb}+\mathrm{SO}_2 \end{array}\right. \end{aligned} $$ (self reduction) In copper metal $$ \begin{aligned} & 2 \mathrm{Cu}_2 \mathrm{~S}+3 \mathrm{O}_2 \longrightarrow 2 \mathrm{Cu}_2 \mathrm{O}+2 \mathrm{SO}_2 \\ & \mathrm{Cu}_2 \mathrm{~S}+2 \mathrm{Cu}_2 \mathrm{O} \longrightarrow 6 \mathrm{Cu}+\mathrm{SO}_2 \end{aligned} $$ (self reduction) (B) Carbon reduction $P$-lead $$ \begin{aligned} & \text { i.e., } \mathrm{B}-\mathrm{P} \\ & \text { In lead metal } \\ & \qquad \mathrm{PbO}+\mathrm{C} \longrightarrow \mathrm{Pb}+\mathrm{CO} \\ & \mathrm{PbO}+\mathrm{CO} \longrightarrow \mathrm{Pb}+\mathrm{CO}_2 \end{aligned} $$ Carbon reduction process is used for the reduction of oxides of electropositive metals like $\mathrm{Fe}, \mathrm{Pb}$ etc. This reduction is carried out with coal or coke on strongly heating. (C) Complex formation and displacement by metal. i.e., $C-Q$ (silver) In silver metal Argentite mineral of $\mathrm{Ag}\left(\mathrm{Ag}_2 \mathrm{~S}\right)$ is treated with $0.7 \% \mathrm{NaCN}$ solution in presence of air, therefore firstly sodium argento cyanide complex is formed which on heating with zinc metal, therefore by displacement silver is isolated. $$ \begin{aligned} & \mathrm{Ag}_2 \mathrm{~S}+4 \mathrm{NaCN} \longrightarrow 2 \mathrm{Na}\left[\mathrm{Ag}(\mathrm{CN})_2\right]+\mathrm{Na}_2 \mathrm{~S} \\ & 2 \mathrm{Na}\left[\mathrm{Ag}(\mathrm{CN})_2\right]+\mathrm{Zn} \longrightarrow \mathrm{Na}\left[\mathrm{Zn}(\mathrm{CN})_4\right]+\underset{\text { Soluble }}{2 \mathrm{Ag}} \downarrow \end{aligned} $$ (D) Decomposition of iodide-(S) Boron $$ \text { i.e., }(D)-(S) $$ By decomposition of iodide boron metal is isolated.

Hence, the correct answer is option: 'D'.

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