Q24 / 180 · COMEDK 2026 (9 May Shift 2) · Chemistry
In the redox reaction, taking place in acidic medium:
$\text{X}\ \text{MnO}_4^-\ (aq) + \text{Y}\ \text{SO}_2(g) \rightarrow \text{Mn}^{+2}(aq) + \text{HSO}_4^-\ (aq)$,
the ratio of X:Y in a stoichiometrically balanced equation will be
$\text{X}\ \text{MnO}_4^-\ (aq) + \text{Y}\ \text{SO}_2(g) \rightarrow \text{Mn}^{+2}(aq) + \text{HSO}_4^-\ (aq)$,
the ratio of X:Y in a stoichiometrically balanced equation will be
- A$1:2$
- B$5:2$
- C$2:3$
- Correct answerD$2:5$
Solution
The given redox reaction can be balanced by splitting it into two half-reactions.
Reduction half-reaction:
$\text{MnO}_4^- + 8\text{H}^+ + 5e^- \rightarrow \text{Mn}^{+2} + 4\text{H}_2\text{O}$
Oxidation half-reaction:
$\text{SO}_2 + 2\text{H}_2\text{O} \rightarrow \text{HSO}_4^- + 3\text{H}^+ + 2e^-$
To equalize the number of electrons transferred, multiply the reduction half-reaction by $2$ and the oxidation half-reaction by $5$:
$2\text{MnO}_4^- + 16\text{H}^+ + 10e^- \rightarrow 2\text{Mn}^{+2} + 8\text{H}_2\text{O}$
$5\text{SO}_2 + 10\text{H}_2\text{O} \rightarrow 5\text{HSO}_4^- + 15\text{H}^+ + 10e^-$
Adding the two balanced half-reactions, we get the overall balanced equation:
$2\text{MnO}_4^- + 5\text{SO}_2 + \text{H}^+ + 2\text{H}_2\text{O} \rightarrow 2\text{Mn}^{+2} + 5\text{HSO}_4^-$
Comparing this with the given equation $\text{X}\ \text{MnO}_4^- + \text{Y}\ \text{SO}_2 \rightarrow \dots$, we find:
$\text{X} = 2$
$\text{Y} = 5$
Therefore, the ratio of $\text{X}:\text{Y}$ is $2:5$.
Answer: $2:5$
Reduction half-reaction:
$\text{MnO}_4^- + 8\text{H}^+ + 5e^- \rightarrow \text{Mn}^{+2} + 4\text{H}_2\text{O}$
Oxidation half-reaction:
$\text{SO}_2 + 2\text{H}_2\text{O} \rightarrow \text{HSO}_4^- + 3\text{H}^+ + 2e^-$
To equalize the number of electrons transferred, multiply the reduction half-reaction by $2$ and the oxidation half-reaction by $5$:
$2\text{MnO}_4^- + 16\text{H}^+ + 10e^- \rightarrow 2\text{Mn}^{+2} + 8\text{H}_2\text{O}$
$5\text{SO}_2 + 10\text{H}_2\text{O} \rightarrow 5\text{HSO}_4^- + 15\text{H}^+ + 10e^-$
Adding the two balanced half-reactions, we get the overall balanced equation:
$2\text{MnO}_4^- + 5\text{SO}_2 + \text{H}^+ + 2\text{H}_2\text{O} \rightarrow 2\text{Mn}^{+2} + 5\text{HSO}_4^-$
Comparing this with the given equation $\text{X}\ \text{MnO}_4^- + \text{Y}\ \text{SO}_2 \rightarrow \dots$, we find:
$\text{X} = 2$
$\text{Y} = 5$
Therefore, the ratio of $\text{X}:\text{Y}$ is $2:5$.
Answer: $2:5$
Hence, the correct answer is option: 'D'.