Q23 / 170 · Manipal (MET) 2015 · Chemistry

In the reaction, $\begin{aligned} 4 M+8 \mathrm{CN}^{-}+2 \mathrm{H}_2 \mathrm{O} & +\mathrm{O}_2 \\ & \longrightarrow 4\left[M(\mathrm{CN})_2\right]+4 \mathrm{OH}^{-}\end{aligned}$ identify the metal $M$.

  • A
    Copper
  • B
    Iron
  • Correct answer
    C
    Silver
  • D
    Zinc

Solution

$4 \mathrm{Ag}+8 \mathrm{CN}^{-}+2 \mathrm{H}_2 \mathrm{O}+\mathrm{O}_2 \longrightarrow 4\left[\mathrm{Ag}(\mathrm{CN})_2 \Gamma^{-}+4 \mathrm{OH}^{-}\right.$ This process is called cynide process. It is used in the extraction of silver from argentite $\left(\mathrm{Ag}_2 \mathrm{~S}\right)$.

Hence, the correct answer is option: 'C'.

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