Q97 / 200 · NEET 2008 (Screening) · Chemistry

In a reaction of aniline a coloured product $C$ was obtained. Figure
$\ ext {The structure of } C \text { would be}$

  • A
    Figure
  • B
    Figure
  • C
    Figure
  • Correct answer
    D
    Figure

Solution

Key Idea : $1^{\circ}$ amines form diazonium salts at low temperature and diazonium salts are weak electrophiles, so react with strongly activated ring. (takes $\mathrm{H}$ from benzene nucleus). Figure
Note : The $-\mathrm{N}=\mathrm{N}-$ linkage is called -azo linkage, and the reactions in which azo or diazo compounds are formed, are called diazo coupling reactions.

Hence, the correct answer is option: 'D'.

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