Q19 / 180 · COMEDK 2023 (Memory Based) · Chemistry

In a $0.2 \mathrm{M}$ aqueous solution, lactic acid is $6.9 \%$ dissociated. The value of dissociation constant is

  • A
    $1.2 \times 10^{-4}$
  • Correct answer
    B
    $95 \times 10^{-4}$
  • C
    $6.5 \times 10^{-4}$
  • D
    $3.6 \times 10^{-2}$

Solution

Given, $\alpha=6.9 \%$ $\therefore$ Degree of dissociation, $\alpha=\frac{6.9}{100}$ $\therefore \quad \alpha=0.069$ According to ostwald's dilution law, $\begin{aligned} & K_a=\alpha^2 C=(0.069)^2 \times 0.2 \\ & K_a=9.5 \times 10^{-4} \end{aligned}$

Hence, the correct answer is option: 'B'.

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