Q18 / 60 · JEE Advanced 2015 (Paper 1) · Chemistry

If the unit cell of a mineral has cubic close packed (ccp) array of oxygen atoms with m fraction of octahedral holes occupied by aluminium ions and n fraction of tetrahedral holes occupied by magnesium ions, m and n, respectively, are

  • Correct answer
    A
    12,18
  • B
    1,14
  • C
    12,12
  • D
    14,18

Solution

In ccp, O2- ions are 4.
Hence total negative charge = -8
Let Al3+ ions be x, and Mg2+ ions be y.
Total positive charge = 3x + 2y
⇒3x+2y=8
This relation is satisfied only by x = 2 and y = 1.
Hence number of Al3+=2
and number of Mg2+=1
⇒ n = fraction of octahedral holes occupied by Al3+
=24=12
and m = fraction of tetrahedral holes occupied by Mg2+
=18

Hence, the correct answer is option: 'A'.

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