Q18 / 60 · JEE Advanced 2015 (Paper 1) · Chemistry
If the unit cell of a mineral has cubic close packed (ccp) array of oxygen atoms with m fraction of octahedral holes occupied by aluminium ions and n fraction of tetrahedral holes occupied by magnesium ions, m and n, respectively, are
- Correct answerA
- B
- C
- D
Solution
In ccp, ions are 4.
Hence total negative charge = -8
Let ions be x, and ions be y.
Total positive charge = 3x + 2y
This relation is satisfied only by x = 2 and y = 1.
Hence number of
and number of
n = fraction of octahedral holes occupied by
and m = fraction of tetrahedral holes occupied by
Hence total negative charge = -8
Let ions be x, and ions be y.
Total positive charge = 3x + 2y
This relation is satisfied only by x = 2 and y = 1.
Hence number of
and number of
n = fraction of octahedral holes occupied by
and m = fraction of tetrahedral holes occupied by
Hence, the correct answer is option: 'A'.