Q21 / 150 · MHT CET 2025 (20 Apr Shift 1) · Chemistry
Identify the product ' B ' in the following sequence of reactions.
Methylpropanoate $\underset{\text { dil. } \mathrm{NaOH}}{\stackrel{\Delta}{\longrightarrow}} \mathrm{A} \xrightarrow[\text { Conc. } \mathrm{HCl}]{\mathrm{H}^{+}} \mathrm{B}$
- Asodium propanoate
- Bpropanone
- Cpropanal
- Correct answerDpropanoic acid
Solution
Hydrolysis of methylpropanoate with dilute sodium hydroxide yields sodium propanoate via saponification:
$\mathrm{CH_3 CH_2 COOCH_3 + NaOH \rightarrow CH_3 CH_2 COONa + CH_3 OH}$
Subsequent acidification with concentrated hydrochloric acid converts the salt to propanoic acid:
$\mathrm{CH_3 CH_2 COONa + H+ \rightarrow CH_3 CH_2 COOH + Na+}$
Thus product B is propanoic acid, corresponding to option D.
Hence, the correct answer is option: 'D'.