Q43 / 150 · MHT CET 2026 (15 April Shift 1) · Chemistry

Identify the compound formed when But-2-ene is treated with $\text{KMnO}_4$ in dilute $\text{H}_2\text{SO}_4$.

  • A
    Butanoic acid
  • Correct answer
    B
    Acetic acid
  • C
    Butanal
  • D
    Butanol

Solution

But-2-ene has the structure $\text{CH}_3-\text{CH}=\text{CH}-\text{CH}_3$.

When treated with acidic $\text{KMnO}_4$ ($\text{KMnO}_4$ in dilute $\text{H}_2\text{SO}_4$), it undergoes oxidative cleavage. The strong oxidizing agent completely breaks the carbon-carbon double bond, oxidizing each of the resulting fragments into a carboxylic acid.

$\text{CH}_3-\text{CH}=\text{CH}-\text{CH}_3 \xrightarrow{\text{KMnO}_4, \text{H}^+} 2 \text{CH}_3\text{COOH}$

The product formed is acetic acid (ethanoic acid).

Answer: Acetic acid

Hence, the correct answer is option: 'B'.

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