Q91 / 200 · NEET 2023 (All India) · Chemistry

Figure

Identify A and B

  • A
    Figure
  • B
    Figure
  • C
    Figure
  • Correct answer
    D
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Solution

Ether when treated with HI produces both benzyl iodide or phenol. Under acidic conditions (i.e., with a small amount of HI), the ether can undergo an acid-catalyzed cleavage to form phenol  and benzyl iodide. In this reaction, the HI acts as a catalyst, and the protonation of the ether oxygen atom makes it a good leaving group, which then departs to form benzyl carbocation. The carbocation can then react with the iodide ion to form benzyl iodide, while the protonated oxygen atom can undergo deprotonation and form phenol.

Figure

Hence, the correct answer is option: 'D'.

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