Q49 / 105 · NTA Abhyas (JEE Main) 2020 · Chemistry · d and f Block Elements

HCN+H2O→X+NH3,

X→Y+H2O Unbalanced equations

[Y] May be prepared by which one of the following methods?

  • A
    By dehydration of Malonic acid with P2O5
  • B
    By thermal decomposition of carbon sub-oxide in air.
  • Correct answer
    C
    By heating potassium hexacyanoferrate (II) with conc. H2SO4 .
  • D
    By the action of conc. HNO3 on charcoal.

Solution

HCN + 2H2O→HCOOHX + 2NH3;
HCOOH→ΔCOY+H2O
(iii) Only K4FeCN6 gives CO with conc. H2SO4 according to the following reaction.
K4FeCN6+6H2SO4conc. + 6H2O→2K2SO4+FeSO4+3NH42SO4+6CO
(i) Malonic acid gives C3O2 ;
(ii) C3O2 gives CO2 .
(iv) Action of conc. HNO3 on charcoal gives CO2 .

Hence, the correct answer is option: 'C'.

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