Q8 / 90 · JEE Main 2022 (27 Jul Shift 1) · Chemistry

Given below are two statements:

Statement I : Hydrogen peroxide can act as an oxidizing agent in both acidic and basic conditions.

Statement II: Density of hydrogen peroxide at 298 K is lower than that of D2O.

In the light of the above statements. Choose the correct answer from the options.

  • A
    Both statement I and Statement II are ture
  • B
    Both statement I and Statement II are false
  • Correct answer
    C
    Statement I is true but Statement II is false
  • D
    Statement I is false but Statement II is true

Solution

It acts as an oxidising as well as reducing agent in both acidic and alkaline media. Simple reactions are described below.

(i) Oxidising action in acidic medium

2Fe2+aq+2H+aq+H2O2aq→2Fe3+aq+2H2Ol

(ii) Reducing action in acidic medium

2MnO4−+6H++5H2O2→2Mn2++8H2O+5O2

(iii) Oxidising action in basic medium

2Fe2++H2O2→2Fe3++2OH-

(iv) Reducing action in basic medium

I2+H2O2+2OH−→2I−+2H2O+O2

The density of hydrogen peroxide is more than that of heavy water

Density of D2O=1.1 g/cc

Density of H2O2=1.45 g/cc

Hence, the correct answer is option: 'C'.

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