Q8 / 90 · JEE Main 2022 (27 Jul Shift 2) · Chemistry

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R

Assertion A: Boron is unable to form BF63-

Reason R: Size of B is very small.

In the light of the above statements, choose the correct answer from the options given below

  • A
    Both A and R are true and R is the correct explanation of A
  • Correct answer
    B
    Both A and R are true but R is not the correct explanation of A
  • C
    A is true but R is false
  • D
    A is false but R is true

Solution

Due to non-availability of d orbitals, boron is unable to expand its octet. Therefore, the maximum covalence of boron cannot exceed 4.

Boron is the first element from top in group 13 and the atomic size increases down the group. Therefore, boron is smallest in size.

Assertion A: True

Reason R: True but not correct explanation.
 

Hence, the correct answer is option: 'B'.

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