Q9 / 90 · JEE Main 2022 (26 Jul Shift 2) · Chemistry

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R. Assertion A : LiF is sparingly soluble in water. Reason R : The ionic radius of Li+ ion is smallest among its group members, hence has least hydration enthalpy.

In the light of the above statements, choose the most appropriate answer from the options given below.

  • A
    Both A and R are true and R is the correct explanation of A
  • B
    Both A and R are true but R is NOT the correct explanation of A
  • Correct answer
    C
    A is true but R is false
  • D
    A is false but R is true

Solution

The low solubility of LiF in water is due to its high lattice enthalpy.

The hydration enthalpies of alkali metal ions in aqueous solution decreases with increase in ionic sizes.

Li+>Na+>K+>Rb+>Cs+

Li+ has maximum degree of hydration and for this reason lithium salts are mostly hydrated, e.g., LiCl.2H2O

Hence, A is true and R is false.

Hence, the correct answer is option: 'C'.

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