Q9 / 90 · JEE Main 2022 (26 Jul Shift 2) · Chemistry
Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason . Assertion : is sparingly soluble in water. Reason : The ionic radius of ion is smallest among its group members, hence has least hydration enthalpy.
In the light of the above statements, choose the most appropriate answer from the options given below.
Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason . Assertion : is sparingly soluble in water. Reason : The ionic radius of ion is smallest among its group members, hence has least hydration enthalpy.
In the light of the above statements, choose the most appropriate answer from the options given below.
- ABoth and are true and is the correct explanation of
- BBoth and are true but is NOT the correct explanation of
- Correct answerCis true but is false
- Dis false but is true
Solution
The low solubility of in water is due to its high lattice enthalpy.
The hydration enthalpies of alkali metal ions in aqueous solution decreases with increase in ionic sizes.
has maximum degree of hydration and for this reason lithium salts are mostly hydrated, e.g.,
Hence, A is true and R is false.
Hence, the correct answer is option: 'C'.