Q9 / 54 · JEE Advanced 2022 (Paper 1) · Chemistry

For diatomic molecules, the correct statement(s) about the molecular orbitals formed by the overlap of two 2pz orbitals is(are)

  • Correct answer
    A
    σ orbital has a total of two nodal planes.
  • B
    σ* orbital has one node in the xz-plane containing the molecular axis.
  • C
    π orbital has one node in the plane which is perpendicular to the molecular axis and goes through the center of the molecule
  • Correct answer
    D
    π* orbital has one node in the xy-plane containing the molecular axis.

Solution

When this orbital combine along the internuclear axis then σ orbital is formed while this orbital approach each other parallel to each other and perpendicular to the internuclear axis π orbital is formed.

Figure

Hence, the correct answer is options: 'A', 'D'.

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