Q12 / 160 · TS EAMCET 2022 (18 Jul Shift 1) · Chemistry

For a reaction As⇌Bs+Cg the set of all correct statements are

a) K is independent of A.

b) K is dependent on partial pressure of C at a given temperature.

c) ΔH will be independent of temperature.

d) ΔH is independent of the catalyst addition.

  • A
    a,b,c,d
  • B
    a,b only
  • Correct answer
    C
    a,b,d only
  • D
    a,b,c only

Solution

Given reaction is 

As⇌Bs+Cg

Equilibrium constant for this reaction KC = C concentration of solid is considered as one during heterogenous equilibrium. So, as we can see K is independent of A.

Similarly KP = PC So, K is dependent on partial pressure of C.

Note: Although the value of equilibrium constant does not depend on concentration of reactants or products at a given temperature.

Enthalpy change depends on temperature, but it is independent of catalyst used.

So, statement a,b and d are correct.

Hence, the correct answer is option: 'C'.

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