Q25 / 180 · JIPMER 2019 · Chemistry

$\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{CH}_2-\mathrm{Br} \xrightarrow{\text { Alc. } \mathrm{KOH}}$ Final product is

  • Correct answer
    A
    propene
  • B
    propanol
  • C
    cyclopropane
  • D
    propane-1, 2-diol

Solution

When haloalkane containing $\beta$-hydrogen atom is heated with alc. KOH solution, then alkene is formed $\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{Br} \xrightarrow{\text { alc. } \mathrm{KOH}} \mathrm{CH}_3 - \underset{\text { Propene }}{\mathrm{CH}}=\mathrm{CH}_2$ In this reaction, hydrogen is elimated from $\beta$-carbon and the halogen is lost from $\alpha$-carbon atom. As a result, an alkene is formed as a product. Due to the involvement of elimination of $\beta$ -hydrogen atom, the process is often called $\beta$-elimination.

Hence, the correct answer is option: 'A'.

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