Q22 / 75 · JEE Main 2025 (24 Jan Shift 1) · Chemistry

Consider the following reaction occurring in the blast furnace: $\mathrm{Fe}_3 \mathrm{O}_{4(\mathrm{~s})}+4 \mathrm{CO}_{(\mathrm{g})} \rightarrow 3 \mathrm{Fe}_{(\mathrm{l})}+4 \mathrm{CO}_{2(\mathrm{~g})}$ ' $x$ ' kg of iron is produced when $2.32 \times 10^3 \mathrm{~kg} \mathrm{Fe}_3 \mathrm{O}_4$ and $2.8 \times 10^2 \mathrm{~kg} \mathrm{CO}$ are brought together in the furnace. The value of ' $x$ ' is _____. (nearest integer) Given: molar mass of $\mathrm{Fe}_3 \mathrm{O}_4=232 \mathrm{~g} \mathrm{~mol}^{-1}$ molar mass of $\mathrm{CO}=28 \mathrm{~g} \mathrm{~mol}^{-1}$ molar mass of $\left.\mathrm{Fe}=56 \mathrm{~g} \mathrm{~mol}^{-1}\right\}$

Correct answer: 420

Solution

$\begin{aligned} & \text { moles of } \mathrm{Fe}_3 \mathrm{O}_4=\frac{2.32 \times 10^3 \times 10^3}{232}=10000 \mathrm{~mol} \\ & \text { moles of } \mathrm{CO}=\frac{2.8 \times 10^2 \times 10^3}{28}=10000 \mathrm{~mol} \\ & \mathrm{Fe}_3^3 \mathrm{O}_4+4 \mathrm{CO} \longrightarrow 3 \mathrm{Fe}+4 \mathrm{CO}_2 \\ & 10^4 \mathrm{~mol} \quad 10^4 \mathrm{~mol} \end{aligned}$ CO is L.R. mole of $\mathrm{Fe}=\frac{3}{4} \times 10^4$ mass of $\mathrm{Fe}=\frac{3}{4} \times \frac{10^4 \times 56}{1000} \mathrm{~kg}=420 \mathrm{~kg}$

Hence, the correct answer is 420.

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