Q39 / 80 · NEST (NISER) 2024 (Session 1) · Chemistry

Consider the following molecular orbitals that are formed by sidewise (or lateral) overlap of adjacent 2 p atomic orbitals of carbons in a conjugated aliphatic chain.
Figure

The correct order of energies of the molecular orbitals is

  • A
    $\mathrm{I} \lt \mathrm{IV}=\mathrm{II} \lt \mathrm{III}$
  • B
    $\mathrm{III} \lt \mathrm{IV} \lt \mathrm{II} \lt \mathrm{I}$
  • Correct answer
    C
    $\mathrm{I} \lt \mathrm{II} \lt \mathrm{IV} \lt \mathrm{III}$
  • D
    $\mathrm{IV}=\mathrm{II}=\mathrm{III} \lt \mathrm{I}$

Hence, the correct answer is option: 'C'.

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