Q17 / 53 · NEST (NISER) 2013 · Chemistry

Atoms A and B are interacting to form bonds $(\sigma, \pi)$. If $z$-axis is taken as the internuclear axis, the correct statement regarding the formation of a bond is

  • A
    $p_z^{\mathrm{A}}$ and $p_z^{\mathrm{B}}$ atomic orbitals contribute to $\pi$ bond.
  • B
    $d_{x^2-y^2}^{\mathrm{A}}$ and $d_{x^2-y^2}^{\mathrm{B}}$ atomic orbitals contribute to $\pi$ bond.
  • C
    $p_y^{\mathrm{A}}$ and $p_y^{\mathrm{B}}$ atomic orbitals contribute to $\sigma$ bond.
  • Correct answer
    D
    $d_{z^2}^{\mathrm{A}}$ and $d_{z^2}^{\mathrm{B}}$ atomic orbitals contribute to $\sigma$ bond.

Hence, the correct answer is option: 'D'.

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