Q9 / 54 · JEE Advanced 2018 (Paper 1) · Chemistry
Consider an ionic solid , with structure. Construct a new structure , whose unit cell is constructed from the unit cell of , following the sequential instructions given below. Neglect the charge balance.
Remove all the anions , except the central one.
Replace all the face centered cations , by anions .
Remove all the corner cations .
Replace the central anion , with cation .
The value of in is _____.
Remove all the anions , except the central one.
Replace all the face centered cations , by anions .
Remove all the corner cations .
Replace the central anion , with cation .
The value of in is _____.
Correct answer: 3
Solution
| (i) | 4 | 1 |
| (ii) | 4 – 3 | 3 + 1 |
| (iii) | 4 – 3 – 1 | 3 + 1 |
| (iv) | 1 | 3 |
Hence, the correct answer is 3.