Q20 / 105 · NTA Abhyas (JEE Main) 2020 · Chemistry · d and f Block Elements

Compounds A and B are treated with dil. HCl separately. The gas liberated are Y and Z respectively. Y turns acidified K2Cr2O7 paper green while Z turns lead acetate paper black. The compounds A and B are respectively.

  • A
    NaCl and Na2CO3
  • Correct answer
    B
    Na2SO3 and Na2S
  • C
    Na2S and Na2SO3
  • D
    Na2SO3 and Na2SO4

Solution

Here A & (B) are Na2SO3andNa2S respectively.
Na2SO3(A)+2HCl→2NaCl+SO2(Y)+H2O
K2Cr2O7+H2SO4+3SO2→K2SO4+Cr2(SO4)3Green+H2O
Na2S(B)+2HCl→2NaCl+H2S(Z)
PbCH3COO2+H2S→PbSBlack+2CH3COOH

Hence, the correct answer is option: 'B'.

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