Q7 / 150 · MHT CET 2025 (25 Apr Shift 2) · Chemistry
Calculate the vapour pressure of solution if relative lowering of vapour pressure and vapour pressure of pure solvent are 0.018 and 18 mm Hg respectively at 300 K .
- A18.32 mm Hg
- B17.08 mm Hg
- Correct answerC17.68 mm Hg
- D18.60 mm Hg
Solution
Vapor pressure lowering is a colligative property described by Raoult's law for non-volatile solutes:
$\frac{P^0 - P_s}{P^0} = \text{relative lowering}$
Given a relative lowering of $0.018$ and a pure solvent vapor pressure $P^0 = 18\text{ mm Hg}$, substitute into the equation:
$\frac{18 - P_s}{18} = 0.018$
Solving for $P_s$:
$18 - P_s = 0.018 \times 18$
$18 - P_s = 0.324$
$P_s = 18 - 0.324 = 17.676\text{ mm Hg}$
Rounded to two decimal places, $P_s = 17.68\text{ mm Hg}$, which corresponds to option C.
Final answer: $\boxed{\text{C}}$
Hence, the correct answer is option: 'C'.