Q17 / 150 · MHT CET 2025 (25 Apr Shift 2) · Chemistry

Calculate the number of moles of nonvolatile solute dissolved in 0.5 kg solvent if molal elevation constant for solvent is $2 \mathrm{~kg} \mathrm{~K} \mathrm{~mol}^{-1}$ $\left[\Delta \mathrm{T}_{\mathrm{b}}=0.8 \mathrm{~K}\right]$

  • A
    0.1
  • Correct answer
    B
    0.2
  • C
    0.3
  • D
    0.4

Solution

The number of moles is determined using the boiling point elevation formula $\Delta T_b = K_b m$, with $\Delta T_b = 0.8\text{ K}$ and $K_b = 2\text{ kg K mol}^{-1}$.

Molality $m$ relates to moles $n$ and solvent mass $0.5\text{ kg}$ as $m = n / 0.5$.

Substituting into the elevation formula:
$0.8 = 2 \cdot \frac{n}{0.5}$

Solving for $n$:
$n = \frac{0.8 \times 0.5}{2} = \frac{0.4}{2} = 0.2\text{ mol}$

The number of moles of nonvolatile solute is $\boxed{0.2}$.

Hence, the correct answer is option: 'B'.

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