Q40 / 160 · TS EAMCET 2019 (04 May Shift 1) · Chemistry

Benzaldehyde can be converted to benzonitrile by treatment with

  • A
    $\mathrm{NH}_3$
  • B
    $\mathrm{NH}_3$ followed by reaction with $\mathrm{C}_6 \mathrm{H}_5 \mathrm{SO}_2 \mathrm{Cl}$
  • Correct answer
    C
    $\mathrm{NH}_2 \mathrm{OH}$ followed by reaction with acetic anhydride
  • D
    $\mathrm{NH}_2 \mathrm{OH}$

Solution

When benzaldehyde reacts with $\mathrm{NH}_2 \mathrm{OH}$ (hydroxyl amine) then oxime is formed. Further oxime gives benzonitrile on heating. Figure
$$ \text { Thus, option (3) is correct. } $$

Hence, the correct answer is option: 'C'.

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