Q25 / 150 · MHT CET 2026 (11 April Shift 1) · Chemistry

At $298$ K, the specific conductance ($\kappa$) of a $0.0020$ M NaCl solution is $2.50 \times 10^{-4} \text{ S cm}^{-1}$. Calculate the molar conductivity ($\Lambda_m$) of the solution in $\text{S cm}^2 \text{ mol}^{-1}$.

  • Correct answer
    A
    $125$
  • B
    $62.5$
  • C
    $12.5$
  • D
    $250$

Solution

Given:

$\kappa = 2.50 \times 10^{-4} \text{ S cm}^{-1}$

$C = 0.0020 \text{ M}$

The molar conductivity $\Lambda_m$ is given by the formula:

$\Lambda_m = \dfrac{\kappa \times 1000}{C}$

Substituting the given values:

$\Lambda_m = \dfrac{2.50 \times 10^{-4} \times 1000}{0.0020}$

$\Lambda_m = \dfrac{0.250}{0.0020}$

$\Lambda_m = 125 \text{ S cm}^2 \text{ mol}^{-1}$

Answer: $125$

Hence, the correct answer is option: 'A'.

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