Q13 / 125 · BITSAT 2020 · Chemistry

Arrange the following ions in the order of decreasing $\mathrm{X}-\mathrm{O}$ bond length, where $\mathrm{X}$ is the central atom

  • A
    $\mathrm{ClO}_{4}^{-}, \mathrm{SO}_{4}^{2-}, \mathrm{PO}_{4}^{3-}, \mathrm{SiO}_{4}^{-}$
  • Correct answer
    B
    $\mathrm{SiO}_{4}^{4-}, \mathrm{PO}_{4}^{3-}, \mathrm{SO}_{4}^{2-}, \mathrm{ClO}_{4}^{-}$
  • C
    $\mathrm{SiO}_{4}^{4-}, \mathrm{PO}_{4}^{3-}, \mathrm{ClO}_{4}^{-}, \mathrm{SO}_{4}^{2-}$
  • D
    $\mathrm{SiO}_{4}^{4-}, \mathrm{SO}_{4}^{2-}, \mathrm{PO}_{4}^{3-}, \mathrm{ClO}_{4}^{-}$

Solution

More will be the electronegativity of $\mathrm{X}$ lesser will be the bond length of $\underline{X}-\mathrm{O}$ bond.

Hence, the correct answer is option: 'B'.

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