Q8 / 75 · JEE Main 2026 (24 January Shift 1) · Chemistry

Arrange the following carbanions in the decreasing order of stability.
Figure
Choose the correct answer from the options given below:

  • A
    I $>$ IV $>$ II $>$ V $>$ III
  • B
    I $>$ II $>$ IV $>$ V $>$ III
  • Correct answer
    C
    IV $>$ I $>$ II $>$ V $>$ III
  • D
    IV $>$ II $>$ I $>$ III $>$ V

Solution

Carbanion stability increases with electron-withdrawing groups (stabilize negative charge) and decreases with electron-donating groups (destabilize negative charge).
IV has CHO (strongly electron-withdrawing by inductive effect), most stable.
I has Br (weakly electron-withdrawing).
II is pure benzyl with resonance from ring.
V has CH₃ (weakly electron-donating).
III has OCH₃ (strongly electron-donating, destabilizes the carbanion).
The critical factor is inductive electron-withdrawing ability:
CHO > Br > H > CH₃ > OCH₃.
Therefore: IV > I > II > V > III.

Hence, the correct answer is option: 'C'.

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