Q149 / 180 · AIIMS 2004 · Physics

$v_{r m s}, v_{a v}$ and $v_{m p}$ are root mean square, average and most probable speeds of molecules of a gas obeying Maxwellian velocity distribution. Which of the following statements is correct?

  • A
    $v_{m s} < v_{a v} < v_{m p}$
  • Correct answer
    B
    $v_{r m s}>v_{a v}>v_{m p}$
  • C
    $v_{m p} < v_{r m s} < v_{a v}$
  • D
    $v_{m p}>v_{r m s}>v_{\alpha v}$.

Solution

$$ \begin{aligned} & \text { } v_{r m s}=\sqrt{\frac{3 K_B T}{m}}=1.73 \sqrt{\frac{K_B T}{m}} \\ & v_{a v}=\sqrt{\frac{8 K_B T}{\pi m}}=1.60 \sqrt{\frac{K_B T}{m}} \\ & v_{m p}=\sqrt{\frac{2 K_B T}{m}}=1.41 \sqrt{\frac{K_B T}{m}} \end{aligned} $$ From these equations, $v_{r m s}>v_{a v}>v_{m p}$.

Hence, the correct answer is option: 'B'.

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