Q21 / 90 · JEE Main 2023 (01 Feb Shift 2) · Chemistry

A metal M crystallizes into two lattices :- face centred cubic (fcc) and body centred cubic (bcc) with unit cell edge length of 2.0 and 2.5A° respectively. The ratio of densities of lattices fcc to bec for the metal M is _______(Nearest integer)

Correct answer: 4

Solution

The density of the crystal lattice can be calculated as follows,

d=Z×MNAa3

Z=effective number of atoms in unit cell(For BCC=2 and FCC=4)

M=Molar mass

NA=Avogadro's number

a=Edge length

dFCCdBCC=4×MwNA×(2)32×MwNA×(2.5)3=3.90

Hence, the correct answer is 4.

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