Q24 / 90 · JEE Main 2022 (26 Jun Shift 2) · Chemistry

A fish swimming in water body when taken out from the water body is covered with a film of water of weight 36 g. When it is subjected to cooking at 100 °C, then the internal energy for vaporization in kJmol-1 is integer]

[Assume steam to be an ideal gas. Given ΔvapH⊖ for water at 373 K and 1 bar is 41.1 kJ mol-1:R=8.31 J K-1 mol-1]

Correct answer: 38

Solution

Weight of water on fish =36 gram

H2Ol→P=1barT=100 °CH2Og;ΔHvap=41.1 kJ mole-1

ΔH=ΔU=ΔngRT

41.1×2=ΔU+2×8.3141000373

ΔU=82.2-6.2=76kJ

so change in internal energy in kJ/mol=762=38kJ/mole

Hence, the correct answer is 38.

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