Q51 / 180 · KCET 2014 · Chemistry

A crystalline solid \( \mathrm{X} \) reacts with dil. \( \mathrm{HCl} \) to liberate a gas \( \mathrm{Y} . \mathrm{Y} \) decolourises acidified \( \mathrm{KMnO}_{4} \).
When a gas ' \( Z \) ' is slowly passed into an aqueous solution of \( Y \), colloidal sulphur is obtained. \( X \)
and \( Z \) could be, respectively

  • A
    \( \mathrm{Na}_{2} \mathrm{SO}_{4}, \mathrm{H}_{2} \mathrm{~S} \)
  • B
    \( N a_{2} S O_{4}, S O_{2} \)
  • C
    \( \mathrm{Na}_{2} \mathrm{~S}, \mathrm{SO}_{3} \)
  • Correct answer
    D
    \( N a_{2} S O_{3}, H_{2} S \)

Solution

The reactions involved are,
Figure

Hence, the correct answer is option: 'D'.

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