Q7 / 54 · NTA Abhyas (JEE Main) 2020 · Chemistry · Redox Reactions

0.1 M KMnO4 is used for following titration. What volume of the solution in mL will be required to react with 0.158 g of Na2S2O3?
Not balanced: S2O32-+MnO4-+H2O→MnO2(s⁡)+SO42-+OH-

  • Correct answer
    A
    26.7 mL
  • B
    50 mL
  • C
    65 mL
  • D
    75 mL

Solution

S+22O32-+MnO4-+H2O→MnO2(s⁡)+S+6O42-+OH-
'n' factor of Na2S2O3=8
'n' factor of KMnO4=3
m.eq of Na2S2O3= m.eq of KMnO4
0.158 158 ×8×1000=0.1×V×3
V=26.7 mL

Hence, the correct answer is option: 'A'.

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