Q16 / 75 · JEE Main 2020 (07 Jan Shift 2) · Chemistry

Within each pair of elements F and Cl , S and Se , and Li and Na , respectively, the elements that release more energy upon an electron gain are

  • A
    Cl,Se and Na
  • Correct answer
    B
    Cl,S and Li
  • C
    F,S and Li
  • D
    F,Se and Na

Solution

(i) Electron affinity of second period p-block element is less than third period p-block element due to small size of second period p-block element, due to small size electron density is more and upcoming electron face extra repulsion, so energy release is less. Hence, EA order: F<Cl.

(ii) Down the group electron affinity decreases due to size increases. EA order: S>Se Li>Na.

Hence, the correct answer is option: 'B'.

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