Q46 / 66 · NTA Abhyas (JEE Main) 2020 · Chemistry · Carboxylic Acid Derivatives

Which reagent can be used to convert a carboxylic acid chloride into a ketone?

  • A
    Chromic acid
  • B
    PCP
  • C
    Diborane, hydrogen peroxide
  • Correct answer
    D
    An organolithium compound

Solution

Carboxylic acid chloride were converted directly in good yields into ketones using excess alkyl lithiumcuprates (R 2 CuLi) .
Figure

Hence, the correct answer is option: 'D'.

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