Q7 / 110 · VITEEE 2022 · Chemistry

Which one of the following is expected to exhibit optical isomerism? (en \(=\) ethylenediamine)

  • A
    cis-[Pt(\(\left.\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right]\)
  • B
    trans-[Pt(\(\left.\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right]\)
  • Correct answer
    C
    cis- \(\left[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2\right]\)
  • D
    trans- \(\left[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2\right]\)

Solution

Figure
Transform of \(\left[\mathrm{M}(\mathrm{AA})_2 \mathrm{a}_2\right]^{\mathrm{n} \pm}\) does not shows optical isomerism.

Hence, the correct answer is option: 'C'.

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