Q23 / 75 · JEE Main 2025 (2 Apr Shift 2) · Chemistry

Which of the following statements are true?
(A) The subsidiary quantum number $l$ describes the shape of the orbital occupied by the electron.
(B)
Figure
is the boundary surface diagram of the $2 p_x$ orbital.
(C) The + and - signs in the wave function of the $2 \mathrm{p}_{\mathrm{x}}$ orbital refer to charge.
(D) The wave function of $2 p_x$ orbital is zero everywhere in the xy plane.

  • A
    (B) and (D) only
  • B
    (A), (B) and (C) only
  • C
    (C) and (D) only
  • Correct answer
    D
    (A) and (B) only

Solution

(A) Azimuthal quantum number $(\ell)$ indicates the shape of orbital occupied by the electron
(B)
Figure
$\mathrm{p}_{\mathrm{x}}$ orbital
(C) The + and - sign in the wave function of $2 p_x$ orbital refer to the sign (Phase) of the wave function, not the charge
(D) The wave function of $2 p_x$ orbital will be zero in yz plane (Nodal plane).

Hence, the correct answer is option: 'D'.

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